I'm not sure when this started, but DevX has a whole area for Visual Studio 2010 articles. They've got handy links to download a trial and a training kit, walkthroughs of creating extensions (a simple blogging one, and adding your own language to the IDE), and lots more. It's a combination of articles, webcasts, and downloads that cover not just Visual Studio but some of the things you can create with it and what's new in related tools. Of course I've seen some of the material before, but that just shows that it's comprehensive. Take a look around!
Click Start a FREE 10-Day trial